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    Flammable gases are essential for many industrial processes. However, these gases also carry significant risks. This column focuses on the characteristics and hazards of flammable gases in industrial settings, and highlights the markets where production, transportation (storage), and generation of these gases take place.
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    Definition of Flammable Gases

    A flammable gas is a gas that burns in the presence of air or oxygen. Due to its usefulness, it is employed in various industrial and household products and processes. However, because they carry the risk of explosion, it is essential to handle them in a manner appropriate to the specific type of gas.

    The international standard for flammable gases is defined in the United Nations GHS document as "a gas having a flammable range with air at 20°C and a standard pressure of 101.3 kPa."

    The following is an excerpt from the United Nations GHS document:

    2.2.2.1 A flammable gas is classified in Category 1A, 1B or 2 according to the following table. Flammable gases that are pyrophoric and/or chemically unstable are always classified in Category 1A.
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    Types of Flammable Gases and Their Hazards

    The hazards associated with flammable gases vary by type, so proper storage and handling practices are crucial. In this section, we introduce the characteristics and risks of three commonly used flammable gases.

    Methane

    Methane (CH4) is widely used as the primary component of natural gas and city gas. It is a colorless, odorless gas, lighter than air, with a molecular weight of 16.04. Its flammable range is between 5 vol% and 15 vol%, and it has an ignition point of 537°C, making it highly flammable. Methane is typically stored under pressure or as a cryogenic liquid in high-pressure containers, kept away from any ignition sources. In the event of a fire, there is a significant risk that the high-pressure containers could overheat, leading the methane inside to expand and causing the entire container to explode. Additionally, the combustion of methane during the fire can produce hazardous gases. Inhalation of highly concentrated methane or carbon monoxide produced by incomplete combustion of methane may also cause oxygen deficiency. To ensure safety, proper ventilation and gas detectors are essential, along with a prompt response in the event of a leakage. Methane's impact on the environment is also significant, as its global warming coefficient is approximately 25 times that of CO2, highlighting the importance of emission reductions.

    Hydrogen

    Hydrogen is a colorless, odorless, and highly flammable gas, with an invisible flame when it burns. It is extremely flammable, with a flammable concentration range between 4.0% and 75% in air. It also has the lowest density of all gases and diffuses easily, making it prone to leaks even through the smallest gaps. Due to its flammability and ease of leakage, careful attention must be paid to its storage. Furthermore, it has the ability to penetrate certain types of metal materials, reducing their strength over time. Safety measures, such as storing hydrogen in well-ventilated areas and installing gas detectors, are important.

    Propane (Gas)

    Propane is a colorless, odorless gas and the main component of liquefied petroleum gas (LPG). It is highly flammable, with a flammable concentration range between 2.1% and 9.5% in air. Propane should be stored in dedicated high-pressure gas containers, and kept in well-ventilated areas away from heat and sparks, or other ignition sources. In the event of a fire, the container may explode, and ruptured cylinders can turn into hazardous flying debris. The fire may also cause effluence of irritating or toxic gases from flammable materials, and inhalation of highly concentrated propane or carbon monoxide produced by incomplete combustion of propane may lead to oxygen deficiency. Safety measures include wearing appropriate respiratory protection and thermal gloves, and installing gas detectors to monitor for leaks.

    Markets Related to Flammable Gases

    Managing flammable gases plays an important role in various markets, including the oil & gas, shipping, and steel manufacturing industries. Let's take a closer look at the markets where processes involving the production, transportation, and generation of flammable gases take place.

    Production: Oil & Gas

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    The oil & gas industry involves the extraction and production of fuels like kerosene, diesel, and gasoline, as well as flammable gases like propane and butane. These are used as raw materials in various products and as energy sources supporting industries. As a result, the oil & gas industry is indispensable to global industries and everyday life. And due to the high flammability of these products, the oil & gas industry is one of the sectors that requires stringent management of flammable gases.

    Additionally, one of the most hazardous gases in this industry is hydrogen sulfide. It is released during various processes such as mining and refining. Hydrogen sulfide is not only highly flammable but also extremely toxic, posing a significant danger. Even in small amounts, inhalation can lead to disorders of the central nervous system, cardiovascular system, and respiratory system.

    To protect workers from these threats, it is essential to install gas detectors in areas where gases may be present, and to provide portable detectors for workers to carry.

    Transportation: Shipping

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    Flammable gases generated in the oil & gas industry must be distributed from refining facilities for use in various industries and households. Ships play a crucial role in the transportation process, with LPG tankers being a prime example.

    LPG is a liquefied form of propane or butane, achieved through compression or cooling. If LPG leaks for any reason, there is a risk of explosion. A fire incident involving a tanker can cause significant damage not only to the ship and workers, but also to port facilities and marine resources. To prevent such accidents, stringent gas management using fixed and portable gas detectors is necessary.

    Generation: Steel manufacturing

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    In the steel manufacturing industry, flammable gases are generated during many processes leading up to the completion of products. For example, in the steel manufacturing process, where iron ore, coal (coke), and limestone are burned, gases such as carbon monoxide and hydrogen are produced. Additionally, high concentrations of carbon monoxide and hydrogen are generated during the blast furnace process of producing pig iron, while carbon monoxide is also produced during the converter and secondary refining processes.

    If these gases leak during any of the processes, they can cause fires, explosions, or carbon monoxide poisoning, depending on the working environment and concentration. However, they also have flammable properties. Therefore, they are safely recovered during the processes and recycled as fuel gases.

    Protecting Workers: Our Gas Detection Solution

    To protect workers, it is crucial to properly detect and strictly manage flammable gases. Here are three of our products designed to protect workers from flammable gases.

    GX-Force is a high-performance gas detector with an integrated pump, ideal for pre-measurement in confined spaces. In such spaces, there is a risk of oxygen deficiency and accumulation of toxic or flammable gases, so pre-measurement before work is crucial to prevent accidents. GX-Force can measure the concentration of 27 types of flammable gases, including hydrogen, and allows you to preset the gas you want to measure. In addition, you can detect gas leaks with the supplied nozzle. After measurement, you can remove the suction tube and attach the small, unobtrusive main unit to the breathing zone enabling real-time safety management during work.

    Riken Keiki's GX-3R and GX-3R Pro are the world's smallest and lightest multi-components gas detector, ideal for safety management of flammable gases. Particularly, GX-3R can detect four components and GX- 3R Pro can detect five components.  With a robust design and high-performance sensors, it provides reliable gas detection even in harsh working environments.
    SD-3 Series is a high-performance, multifunctional gas detector suitable for large-scale plant facilities such as petrochemical plants. It continuously monitors flammable gases, toxic gases, and oxygen, and issues alarms when gas leakage is detected. With a robust stainless-steel structure, wide operating temperature range (-40°C to +70°C), and diverse installation options, it can adapt to various environments. It is also equipped with the "F Sensor," a RIKEN KEIKI original smart sensor with a three-year warranty, ensuring high-precision gas detection.
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    With a history spanning 85 years, our company has responded to a wide range of customer needs by expanding our product range, enhancing after-sales service, and establishing development and manufacturing bases. By leveraging our unique next-generation sensor technology, we ensure your safety with quick detection, accurate concentration display, and alerting workers. If you need to ensure safety when handling industrial flammable gases, please feel free to contact us for our wide range of products.